porous diaphragm fuel cell

SUBJECT AREA: Electricity

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After education at Brasenose College, Oxford, Grove was called to the Bar in 1835. Instead of immediately practising, he became involved in electrical research, devising in 1839 the cell that bears his name. He became Professor of Experimental Philosophy at the London Institution from 1840 to 1845; it was during this period that he built up his high reputation among physicists. In 1846 he published On the Correlation of Physical Forces, which was based on a course of his lectures. He returned to the practice of law, becoming a judge in 1871, but retained his interest in scientific research during his sixteen-year occupancy of the Bench. He served as a member of the Council of the Royal Society in 1846 and 1847 and played a leading part in its reform. Contributing to the science of electrochemistry, he invented the Grove cell, which together with its modification by Bunsen became an important source of electrical energy during the middle of the nineteenth century, before mechanically driven generators became available. The Grove cell had a platinum electrode immersed in strong nitric acid, separated by a porous diaphragm from a zinc electrode in weak sulphuric acid. The hydrogen formed at the platinum electrode was immediately oxidized by the acid, turning it into water. This avoided the polarization which occurred in the early copper-zinc cells. It was a very powerful primary cell with a high voltage and a low internal resistance, but it produced objectionable fumes. Grove also invented his "gas battery", the earliest fuel cell, in which a current resulted from the chemical energy released from combining oxygen and hydrogen. This was developed by Rawcliffe and others, and found applications as a power source in manned spacecraft.

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